A recent Geoscience Australia sampling survey in the Bight Basin recovered hundreds of dredge samples of Early Cenomanian to Late Maastrichtian age. Given the location of these samples near the updip northern edge of the Ceduna Sub-basin, they are all immature for hydrocarbon generation with vitrinite reflectance - 0.5% RVmax, Tmax < 440oC and PI < 0.1. Excellent hydrocarbon generative potential is seen for marine, outer shelf, black shales and mudstones with TOC to 6.9% and HI up to 479 mg hydrocarbons/g TOC. These sediments are exclusively of Late Cenomanian-Early Turonian (C/T) in age. The high hydrocarbon potential of the C/T dredge samples is further supported by a dominance of the hydrogen-rich exinite maceral group (liptinite, lamalginite and telalginite macerals), where samples with the highest HI (> 200 mg hydrocarbons/g TOC) contain > 70% of the exinite maceral group. Pyrolysis-gas chromatography and pyrolysis-gas chromatography mass spectrometry of the C/T kerogens reveal moderate levels of sulphur compounds and the relative abundances of aliphatic and aromatic hydrocarbons predict the generation of a paraffinic-naphthenic-aromatic low wax oil in nature. Not enough oom for rest of Abstract

The 50 major Australian source rock units can be grouped according to age into 15 intervals comprising Late Neoproterozoic, Middle Early Ordovician, late Early Ordovician, Middle to Late Devonian, Early Carboniferous, Early to early Late Permian, late Late Permian, Early to Middle Triassic, Early to Middle Jurassic, Middle to Late Jurassic, Late Jurassic, latest Jurassic to Early Cretaceous, Early Cretaceous, Late Cretaceous, latest Cretaceous to Eocene. Only marine source rocks are known older than Permian, while both marine and nonmarine source rocks are known from Permian and younger intervals. As expected, the marine source rocks are more common where there is a greater degree of continental inundation, while nonmarine source rocks are present only when the continent was at higher palaeolatitudes and when there was at least a moderate amount of continental inundation.

This Record presents a summary of an analysis of 21 offshore Otway Basin wells (Appendix 1) based on data provided in open file Well Completion Reports (WCRs) and Geoscience Australia online databases. Additional data and interpretations are drawn from the large body of published material on the basin. Analysis was inhibited in some cases by the quantity of data in WCRs, specifically the paucity of maps provided in the interpretive sections. Fortunately, most well analyses appear to have a determination of the reason/s for failure that is reasonably clear even without maps. The end product is primarily focused on individual well results, specifically success and failure analysis. To put the wells in a geological perspective, the introduction outlines briefly the regional geologic setting, distilling the ideas of many workers through the basin's exploration history. The final section presents a petroleum systems focused summary of the main findings of the work. From this, critical risks have been identified and areas of higher or additional potential have been indicated.

The carbon and hydrogen isotopic data of natural gases provide a crucial tool to interpret the origin, occurrence and inter-relationships of natural gases. The CF-GC-IRMS is a convenient system to separate gas mixture and obtain continuous, on-line isotopic data of individual compounds. With CF-GC-IRMS system, the abundance of target components is crucial. For an accurate result, there should be enough target compound going through the furnace to be measured as CO2 using isotopic ratio mass spectrometry. For carbon isotopes, a m/z 44 response below 0.3 V (or over 7V) is regarded as unreliable. For high abundant compounds, there is no difficulty in attaining a voltage over 0.3V with a normal injection of under 100ul with adjusted split flow. However, the acquisition for the low concentration component is problematic since "normal" injection would not produce a strong enough signal. In this presentation, we demonstrated the techniques used to obtain low concentration components occurring in the Australian natural gases and how we apply the results in gas comparison studies. Cryogenics (liquid nitrogen trap) is applied to trap and concentrate low amount of compounds other than methane (C1), including CO2, C2 and above. With this method, extreme low concentration of C2 from very dry gases was obtained with large volume injection of 10ml. Back-flash is used together with cryogenics. For analyses for only C4 and C5 compounds, cryogenics was not needed, since they focus at the front of the column at 40oC and elute from the column under oven temperature programming as single peaks. Neo-pentane (neo-C5) is generally the least abundant wet gas component. Its concentration is enhanced in the gases which are biodegraded, wherein the other gas components have been selectively removed by microbial activity. Neo-pentane is extremely resistant to biodegradation and shows no isotopic alteration even in severely biodegraded gas. In such cases, neo-C5 is the only gas component that can be confidently used in gas-gas correlation. Neo-pentane is an example where we employ injection of a large volume (e.g. to 40ml for hydrogen isotopes), combining a back-flashing technique for compounds eluting before C4 (inclusive) and C5 compounds. The neo-C5 elutes between nC4 and i-C5. Under the current GC conditions, there is a time "window" of less than 40 seconds to capture neo-C5. A manual operation to set back-flash to straight flow to allow capture neo-C5 just after n-C4 elutes and then back to back-flush to eliminate interference of C5's compounds. Mass balance estimation indicates that there is no loss of neo-C5 during the large volume injection and repeatability is excellent.

At this scale 1cm on the map represents 1km on the ground. Each map covers a minimum area of 0.5 degrees longitude by 0.5 degrees latitude or about 54 kilometres by 54 kilometres. The contour interval is 20 metres. Many maps are supplemented by hill shading. These maps contain natural and constructed features including road and rail infrastructure, vegetation, hydrography, contours, localities and some administrative boundaries. Product Specifications Coverage: Australia is covered by more than 3000 x 1:100 000 scale maps, of which 1600 have been published as printed maps. Unpublished maps are available as compilations. Currency: Ranges from 1961 to 2009. Average 1997. Coordinates: Geographical and either AMG or MGA coordinates. Datum: AGD66, GDA94; AHD Projection: Universal Transverse Mercator UTM. Medium: Printed maps: Paper, flat and folded copies. Compilations: Paper or film, flat copies only.

Presentation delivered on 9 March 2012 by Marita Bradshaw.

No abstract available

The transgression of coal depositional systems by marine waters enables the preservation of functionalised lipids, such as steranes, hopanes and higher plant triterpanes, via their reaction with reduced inorganic sulphides produced by sulphate-reducing bacteria. Using compound specific isotopic analysis, higher plant and microbial sources of these lipids can be identified. The carbon isotopic compositions of the lipids are invariant to differences in the degree or timing of marine incursion. This indicates that the introduction of marine waters at any stage of mire and peat development preserves the inherited lipid composition and does not overwhelm this biotic signature during sulphate reduction. Consequently, the selective preservation of certain biomarkers enables their use in the reconstruction of coal palaeoenvironments and facilitates oil-source rock correlations. The presence of these coal-derived chemical markers in crude oils is testament to the petroleum generation potential of marine-influenced coals.

Collation of talks and posters completed under the APCRC Program 5 during June 1999-June 2001.

The molecular composition of fluid inclusion (FI) oils from Leander Reef-1, Houtman 1 and Gage Roads-2 provide evidence of the origin of palaeo-oil accumulations in the offshore Perth Basin. These data are complemented by compound specific isotope (CSI) profiles of n-alkanes for the Leander Reef-1 and Houtman-1 samples, which were acquired on purified n-alkane fractions gained by micro-fractionation of lean FI oil samples, showing the technical feasibility of this technique. The Leander Reef-1 FI oil from the top Carynginia Formation shares many biomarker similarities with oils from the Dongara and Yardarino oilfields, which have been correlated with the Early Triassic Kockatea Shale. However, the heavier isotopic values for the C15-C25 n-alkanes in the Leander Reef-1 FI oil indicate that it is a mixture, and suggest that the main part of this oil (~90%) was sourced from the more terrestrial and isotopically heavier Early Permian Carynginia Formation or Irwin River Coal Measures. This insight would have been precluded when looking at molecular evidence alone. The Houtman-1 FI oil from the top Cattamarra Coal Measures (Middle Jurassic) was sourced from a clay-rich, low sulphur source rock with a significant input of terrestrial organic matter, deposited under oxic to suboxic conditions. Biomarkers suggest sourcing from a more prokaryotic-dominated facies than for the other FI oils, possibly a saline lagoon. The Houtman-1 FI oil ?13C CSI data are similar to data acquired on the Walyering-2 oil. Possible lacustrine sources include the Early Jurassic Eneabba Formation or the Late Jurassic Yarragadee Formation. The low maturity Gage Roads-2 FI oil from the Carnac Formation (Early Cretaceous) was derived from a strongly terrestrial, non-marine source rock containing a high proportion of Araucariacean-type conifer organic matter. It has some geochemical differences to the presently reservoired oil in Gage Roads-1, and was probably sourced from the Early Cretaceous Parmelia Formation.